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Using isobutylene as an alkylation reagent requires a reaction under closed conditions, which can also be catalyzed by strong acids. In a mixed solvent of xylene and ketone, 85% phosphoric acid is used as a catalyst [8], and isobutylene is added to synthesize tert butylhydroquinone. The selectivity of the single tert butylation reaction can reach over 90%. Cationic resin [9] can also serve as a catalyst for this reaction, but the effect is not very ideal.
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This may be due to TBHQ being more prone to volatilization under high temperature conditions and losing its effectiveness, and under certain conditions, TBHQ may volatilize faster than BHT. Therefore, the application of microcapsule technology can solve this problem under high temperature conditions.
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At high temperatures, a series of complex chemical reactions such as oxidation, decomposition, polymerization, and hydrolysis are prone to occur, resulting in a rapid increase in the acid value, peroxide value, and carbon base value of roasted foods. In the later stage of storage and sales, unpleasant odors are easily produced. The use of TBHQ can effectively delay oil oxidation in pastry foods.Baked pastry foods require a higher temperature during the baking process, such as cakes and bread, which require a baking temperature of 160C~190C.
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Introduction of nature:TBHQ is almost insoluble in water (about 5‰), soluble in ethanol, acetic acid, ethanol, isopropyl alcohol, ether and vegetable oil, lard, etc., almost insoluble in water (25℃, <1%). Boiling point 295℃, melting point 126 -128.5℃. It has the effect of preventing the failure of most fats and oils, especially vegetable oils. It does not change color in contact with iron and copper, but can turn pink if alkali is present.
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Introduction of nature:TBHQ is sort of insoluble in water (approximately five‰), soluble in ethanol, acetic acid, ethanol, isopropyl alcohol, ether and vegetable oil, lard, and so forth. Nearly insoluble in water (25℃, <1%). Boiling factor 295℃, melting factor 126 -128.5℃. It has the effect of stopping the failure of most fats and oils, specially vegetable oils. It does no longer trade color in touch with iron and copper, but can turn red if alkali is present.
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Hydroquinone  Uses:In medicine, hydroquinone is mainly used in the treatment of pigmented skin diseases, such as chloasma and freckles, etc.
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Physical and chemical properties:Density: 1.328g/cm3Melting point: 172-175℃Boiling point: 286℃Flash factor: 141.6Refractive index: 1.612Vital temperature: 549.9℃Crucial stress: 7.45mpaIgnition temperature: 516℃Explosion limit (v/v): 15.3%Lower explosion restrict (v/v): 1.6 %Property: White needle crystal, discolored through light, with special odor.Solubility: Soluble in hot water, soluble in bloodless water, ethanol and ether, slightly soluble in benzene. Packaging, storage, transportation:1: 25kg (internet weight) kraft paper laminated bag, coated with double polyethylene plastic bag.2:
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Physical and chemical properties:Density: 1.328g/cm3Melting point: 172-175℃Boiling point: 286℃Flash point: 141.6Refractive index: 1.612Critical temperature: 549.9℃Critical pressure: 7.45MPaIgnition temperature: 516℃Explosion limit (V/V): 15.3%Lower explosion limit (V/V): 1.6 %Property: white needle crystal, discolored by light, with special odorSolubility: soluble in hot water, soluble in cold water, ethanol and ether, slightly soluble in benzene Packaging, storage, transportation:1: 25KG (net weight) kraft paper laminated bag, lined with double polyethylene plastic bag.2: Store in a cool
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Corn oil antioxidant TBHQ, also known as tert-butylhydroquinone, white crystalline powder with a point of 126.5-128.5 ℃ point of 300 ℃ CAS No.: 1948-33-0, easily soluble in alcohols and waking up to the majority of fats and oils, especially vegetable oils antioxidant function of the most effective.
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Product ParametersSunflower oil antioxidant TBHQ, i.e. TBHQ, is a white or slightly reddish-brown crystalline powder with a very light special fragrance, almost insoluble in water (about 5 per cent), soluble in ethanol, ethyl acetate, ether and other organic solvents.How to use the productPumping methodSeed method of preparation of TBHQ concentrated solution, through the stainless steel quantitative pump in accordance with the prescribed ratio of injection needs to be stabilized with a fixed flow rate, flow rate of fat or oil in the pipeline.
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TBHQ, also known as tert butyl hydroquinone, is a phenolic oil soluble antioxidant. TBHQ has high efficiency and stability.The US Food and Drug Administration (FDA) allows TBHQ to be used alone or in combination (with BHA or BHT) for oil or fatty foods, including volatile essential oils, with a maximum allowable dosage of 200PPM. The national hygiene standard number is GB276090.4007.The safety of TBHQ has been comprehensively reported, and its acute toxicity belongs to low toxicity level.
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How to use the productDirect methodHeat the grease to 60~70°C, add TBHQ according to the required proportion amount, stir vigorously for 10~15 minutes to dissolve it then stir continuously (no need to stir vigorously to avoid excessive air entry) for about 20 minutes to ensure the TBHQ is evenly distributed.Seed methodFirst dissolve TBHQ in a small amount of oil (or 95% alcohol solution), formulated as 5% ~ 10% of TBHQ oil (or alcohol solution), then directly or by the dosage added to the fat or oil to go and then stir, so that TBHQ uniform distribution.CaveatTBHQ should be fully soluble and e
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Molecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0Product Characteristics1. Tertiary butylhydroquinone is a highly efficient, low-toxicity antioxidant phenolic antioxidant with excellent antioxidant effect, and with the existing food antioxidants BHA, BHT, PG, etc. Comparison of antioxidant capacity as high as 5-7 times2. synergistic: with other antioxidants (such as BHA, B HT) and chelating agents (such as citric acid, etc.) together, there is a synergistic effect.3.
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Product ApplicationsAntioxidants in soybean oil antioxidant effect in the following order: TBHQ>Vc>VE>Catechin>BHT, of which TBHQ, VE and BHT oil solubility is good, heat does not occur after the colour change, suitable for use as a high-grade soybean oil antioxidant.
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Fully dissolve and evenly disperse TBHQ in oil, otherwise it will affect the antioxidant effect.Some organic acids and their derivatives can enhance the activity of TBHQ. It is better to mix it with 0010.02% citric acid.This product cannot be mixed with PG (Propyl Gallate) for use. Avoid using this product under strong alkaline conditions.Oil is one of the basic nutrients in human diet, and most foods contain abundant oil. It can be said that human health cannot do without oil, and the quality and safety of oil are closely related to human health.
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Although some people don't know about the Antioxidant (oil-soluble) TBHQ , Antioxidant (oil-soluble) TBHQappears in all corners of our lives and quietly improves our quality of life.Product Parameters:Molecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0TBHQ is a highly effective and safe food antioxidant, which has been approved for use in more than one hundred countries and regions around the world, including Europe, America, Asia, Australia, Africa, etc.
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The main mechanism of TBHQ is to provide hydrogen to the free radicals R or RO0 in oils and fats, which can form stable dimers and become relatively stable substances.Temperature is the most important factor affecting oil oxidation, similar to general chemical reactions. As the temperature increases, the automatic oxidation rate of oil in the food increases. For every 10C increase in temperature. In addition, essential fatty acids such as linoleic acid and linolenic acid in oil are also damaged, reducing the nutritional function of the product.
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1.Product ParametersTert-butylhydroquinone (TBHQ), also known as tert-butylhydroquinone, white crystalline powder with a point of 126.5-128.5 ℃ point of 300 ℃ CAS No.: 1948-33-0, easily soluble in alcohols and waking up to the majority of fats and oils, especially vegetable oils antioxidant function of the most effective. Tertiary butylhydroquinone (t butylhydroquinone), referred to as TBHQ molecular formula for CH1402, molecular weight of 166.22.2.Academic research and developmentLtd.
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1.Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0The oil in oily food undergoes oxidation in the air, producing free radicals and peroxides, which are early indicators of food rancidity. Peroxides further decompose to form small organic compounds such as aldehydes, ketones, and acids, which directly affect the taste and flavor of the product and cause great harm to human health.
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More than 20 countries have approved the use of TBHQ as a food antioxidant, including China, the United States, Australia, Brazil, etc. The US Food and Drug Administration (FDA) allows TBHQ to be used alone or in combination (with BHA or BHT) for oil or fatty foods, including volatile essential oils, with a maximum allowable dosage of 200PPM. It can also be used in non-alcoholic beverages, margarine, and mixed nuts.China allows TBHQ to be used as a food additive, with a maximum dosage of 0.2g/Kg.
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2-tert-butylhydroquinone is white to light grey crystalline or crystalline powder, with very slight special smell, soluble in ethanol, acetic acid, ethyl alcohol, isopropyl alcohol, ethyl alcohol and oil, etc., a few are insoluble in water (25 ℃ <1%: 95 ℃ <5%) TBHQ is a kind of oil-soluble antioxidant, which can prevent or prolong the oxidation of the fat and oil deterioration in food.2.Product Characteristics2-Tert-butylhydroquinone is a highly efficient, low-toxic antioxidant phenolic antioxidant with excellent antioxidant effect, and the existing food antioxidants BHA, BHT, PG, etc.
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In the United States and China, the maximum allowable dosage of TBHQ in food is 200ppm,At present, the production of tert butyl hydroquinone both domestically and internationally adopts the tert butylation method of hydroquinone, as shown in Figure 2. According to different classifications of alkylation reagents.Both domestic and foreign patent literature have reported this process, such as using toluene or xylene as solvents, the selectivity and yield of this reaction are relatively ideal.
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P-Hydroquinone, known as hydroquinone or hydroquinone in Chinese, is an important organic compound with the chemical formula C6H6O2 and a white crystalline form. This compound has a wide range of applications in the chemical industry, the pharmaceutical field, and the photographic industry. In terms of uses, P-Hydroquinone is mainly used in the production of black and white developers, anthraquinone dyes, azo dyes and so on. In the rubber industry, it is often used as an antioxidant, which helps to extend the service life of rubber products.
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Product DescriptionIn addition, TBHQ also has characteristics such as high temperature resistance, oil solubility, and antibacterial properties, which are widely used in edible oils, fried foods, etc. By comparing the effects of various antioxidants in different products, summarizing the usage patterns, and providing theoretical basis for the application of TBHQ.The oil in oily food undergoes oxidation in the air, producing free radicals and peroxides, which are early indicators of food rancidity.
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Relate News
TBHQ, also known as Tert-Butylhydroquinone, is a food additive that is a synthetic chemical widely used in the food industry to extend the shelf life of foods and prevent oxidation.TBHQ is produced by reacting hydroquinone with tert-butyl alcohol to produce TBHQ, a process that uses advanced technology and strict controls to ensure the high purity and stability of the product.The multiple uses of TBHQ in the food industry are mainly for preventing the oxidation of fats and oils during food processing and storage, thus extending the shelf life of food products.
DTBHQ and TBHQ are two food additives that are somewhat similar in function, but also differ in chemical structure and application areas. Let's take a look at the differences between these two food additives.First of all, there are differences in the chemical structures of DTBHQ and TBHQ, whose full name is Di-Tert-Butylhydroquinone, a di-tert-butylhydroquinone, and TBHQ, whose full name is Tert-Butylhydroquinone, also a hydroquinone, but it has only one tert-butyl group.
Precautions for use 1. The amount and proportion of terbutylhydroquinone used should be strictly controlled and should not exceed the maximum amount specified.2. Terbutylhydroquinone should be used in acidic medium, avoid mixing with alkaline substances.3. Terbutylhydroquinone should be stored in a cool and dry place, avoiding direct sunlight and high temperature environment.4. butylhydroquinone should be stored in stainless steel or glassware when in direct contact with food, avoid using plastic containers.5.
Chinese nameHydroquinoneForeign nameHydroquinoneAliasHydroquinone, 1,4-benzenediolChemical formulaC6H6O2Molecular weight110.111CAS registration number123-31-9EINECS number204-617-8Melting point172 to 175 °CBoiling point286 °CDensity1.328 g/cm³AppearanceWhite crystalline powderFlash point141.6 ℃ApplicationBlack and white developer, anthraquinone dyes, azo dyes, rubber antioxidant, stabilizer and antioxidantSafety descriptionS26; S36/37/39; S61Hazard SymbolsXn; NHazard Descriptionr22; r40; r41; r43; r50; r68UN Dangerous Goods Number2662Soluble in alcohols and ethers, soluble in water, slightly s
Abstract: The Ministry of Health announced 4 national food safety standards in the Ministry of Health Announcement No. 12 in 2011, one of which is "GB 2760-2011 Food Safety National Standard Food Additives Use Standard", which was issued in June 2011 It will be officially implemented on the 20th. The preface of the standard clearly points out that some food classification systems of the 2007 edition of "GB 2760-2007 Hygienic Standards for the Use of Food Additives" have been adjusted.
Zibo, June 25 -- In order to further improve product quality and optimize production processes, a four-member Shandong Best Each team went to Zibo Taiji Enamel Equipment Manufacturing Co. The focus of the visit was on the understanding and learning of core equipment such as enameled reactors and stirred condensers, aiming to promote the leap of product quality and significantly improve the production efficiency through the introduction of more advanced technology and equipment. Zibo Taiji Enameling Equipment Manufacturing Co., Ltd.
Another shipment to Chiping from Shandong Best Each Technology Co.Ltd.
Shandong Best Each Food Technology Co., Ltd. (hereinafter referred to as “Best each”)has successfully completed the shipment of a batch of high-quality food products to the beautiful coastal city of Lianyungang.
Shandong Best Each shipment praised: quality products and excellent transportation build trust, TBHQ anti-fisheye agent shows its magic ability In the vast commercial ocean, Shandong Best Each has won the praise and trust of customers with its excellent product quality and outstanding transportation service.
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