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This may be due to TBHQ being more prone to volatilization under high temperature conditions and losing its effectiveness, and under certain conditions, TBHQ may volatilize faster than BHT. Therefore, the application of microcapsule technology can solve this problem under high temperature conditions.
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Scope of applicationAccording to GB2760(0.4007), the hygienic standard of the People's Republic of China for the use of food additives, TBHQ can be used in edible fats and oils, deep-fried food, dried fish products, biscuits, instant noodle, instant rice, canned dried fruits, cured meat products, roasted and stir-fried nuts (February 2007 supplement), etc. The maximum use level is 0.2g/kg, and the general recommended use level is 0.01~0.02% of the total amount of fats and oils.
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The product is high-quality and cost-effective, making it very suitable for enterprises such as edible oils and instant noodles to use.TBHQ can be used for edible oils, fried foods, dried fish products, biscuits, instant noodles, instant boiled rice, canned dried fruits, pickled meat products, roasted and fried nut foods (supplemented in February 2007), etc. One dose is versatile and can effectively inhibit the growth of bacteria and molds.
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According to the hygiene standard GB2760 (0.4007) for the use of food additives in the People's Republic of China, TBHQ can be used for edible oils, fried foods, dried fish products, biscuits, instant noodles, instant boiled rice, canned dried fruits, pickled meat products, roasted and fried nut foods (supplemented in February 2007), etc. The maximum usage is 0.2g/kg. It is generally recommended to use 0.01~0.02% of the total amount of oil.One dose is versatile and can effectively inhibit the growth of bacteria and molds.
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Product Parameters:Lard antioxidant TBHQ is white to light grey crystalline or crystalline powder, with very slight special smell, soluble in ethanol, acetic acid, ethyl alcohol, isopropyl alcohol, ethyl alcohol and oil, etc., a few are insoluble in water (25 ℃ <1%: 95 ℃ ﹤ 5%) TBHQ is a kind of oil-soluble antioxidant, which can prevent or prolong the oxidation of oil and fat deterioration in food.Product Applications:At present, the most commonly used antioxidants in fats and oils and their products are BHA, BHT, PG, TBHQ and tocopherol.
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It can be seen that various antioxidants have significant antioxidant effects, with the order of advantages and disadvantages being TBHQ>PG>BHA>BHT>tocopherol.And the antioxidant effect increases with the increase of the addition amount; The use of a small amount of synergist in combination with TBHQ can have a synergistic effect on antioxidant activity and enhance its antioxidant effect.Especially in areas with high room temperature, such as some southern regions of China, the sourness and flavor of instant noodles have become a hot topic of concern for instant noodle production e
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Vegetable oils and fats antioxidant TBHQ is a highly efficient, low-toxicity antioxidant phenolic antioxidant with excellent antioxidant effect, and the existing food antioxidant BHA, BHT, PG, etc.
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The experimental results show that adding 002% TBHQ to oil can increase the antioxidant stability of the tested oil by 2-5 times, thus extending the shelf life of oil based foods compared to adding traditional antioxidants; And the antioxidant effect increases with the increase of the addition amount; The use of a small amount of synergist in combination with TBHQ can have a synergistic effect on antioxidant activity and enhance its antioxidant effect; The antioxidant effect of TBHQ on different oils is not entirely related to the iodine value, so further research on its application and develo
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1.Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0Antioxidant TBHQ is a highly effective and safe food antioxidant, which has been approved for use in more than one hundred countries and regions around the world, including Europe, America, Asia, Australia, Africa, etc.
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The seed method first completely dissolves TBHQ in a small amount of oil or 95% alcohol solution, and prepares 5-10% TBHQ oil or alcohol solution. One dose is versatile and can effectively inhibit the growth of bacteria and molds. Within the scope of added applications, it can inhibit the growth of almost all bacteria and yeast, and has a good inhibitory effect on mold harmful to human health such as Aspergillus flavus.The antioxidant effect of this product is very ideal, 5-7 times stronger than BHA, BHT, and PG.
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With the development of farming and pet industry, the market demand for feed is increasing day by day, feed antioxidant TBHQ into the people's vision.1.Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0The experimental results show that adding 002% TBHQ to oil can increase the antioxidant stability of the tested oil by 2-5 times, thus extending the shelf life of oil based foods compared to adding traditional antioxidants; And the antioxidant effect increases with the increase of the addition amount; The use of a small amount of synergist in combination
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Product ApplicationsSuch as soybean oil, due to the presence of a large number of polyunsaturated fatty acids composed of glycerol vinegar (linoleic acid 52%, linolenic acid 8%), by the action of light, heat and air is easy to oxidative deterioration.
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Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0 TBHQ has been used in more than 20 countries, such as the United States, and was approved to be used in oil and fat-containing foods, fish products, biscuits, quick-cooking noodles, canned fat-containing foods, cured meat products in China in 1992.
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Introduction of nature:TBHQ is almost insoluble in water (about 5‰), soluble in ethanol, acetic acid, ethanol, isopropyl alcohol, ether and vegetable oil, lard, etc., almost insoluble in water (25℃, <1%). Boiling point 295℃, melting point 126 -128.5℃. It has the effect of preventing the failure of most fats and oils, especially vegetable oils. It does not change color in contact with iron and copper, but can turn pink if alkali is present.
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Oil and grease antioxidant TBHQMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0TBHQ is an efficient and safe food antioxidant, which has been approved for use in more than one hundred countries and regions around the world, such as Europe, America, Asia, Australia, Africa, etc.
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Oil and grease antioxidant TBHQMolecular method: c10h14o2Molecular weight: 166.22Cas no: 1948-33-zeroTBHQ is a good and secure food antioxidant, which has been accepted to be used in multiple hundred international locations and regions around the world, together with europe, the usa, asia, australia, africa, etc.
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The order of antioxidant activity in soybean oil is TBHQ>Vc>VE>catechins>BHT. Among them, TBHQ, VE, and BHT have good oil solubility and do not change color after heating, making them suitable for use as advanced soybean oil antioxidants. The antioxidant effect of BHT can only be displayed after a long time. Adding 20mg/kg to oil for short-term storage is better than adding 100mg/kg. Although Vc and catechins have strong antioxidant effects, they are difficult to dissolve in oil and have poor thermal stability.
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1.Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-02.Product AdvantagesIn the production of PVC plastic film in the process of often appear some like 'fish-eye' things, the so-called 'fish-eye' in fact is the PVC plastic in the plasticization process fails to plasticize the look similar to the fish's eyes of the spots or transparent hard particles, PVC anti-fish-eye agent TBHQ is to solve this problem!3.Cooperative enterprisesWith the unique and excellent synthesis process, high quality and high purity products, Shandong BEST Food Techn
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The seed method first completely dissolves TBHQ in a small amount of oil or 95% alcohol solution, and prepares 5-10% TBHQ oil or alcohol solution.
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( 1)Stability in chemical reactionParylene is more effective in stabilizing the reaction process, but it discolors the resin.
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At present, the most commonly used antioxidants for oils and their products are BHA, BHT, PG, TBHQ, and tocopherols. As for vegetable oils, their antioxidant capacity is in the order of TBHQ>PG>BHT>BHA. As for animal fats, the order of their antioxidant capacity is TBHQ>PG>BHA>BHT. For anhydrous milk fat, their antioxidant capacity is in the order of PG>TBHQ>BHA>tocopherols.
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The seed method first completely dissolves TBHQ in a small amount of oil or 95% alcohol solution, and prepares 5-10% TBHQ oil or alcohol solution. Then, directly or with a measuring device, it is added to the fat or oil and stirred evenly.The pumping method injects the TBHQ concentrated solution prepared by the seed method into a pipeline with a fixed flow rate and flow rate of fat or oil that needs to be stable at a specified proportion through a stainless steel quantitative pump.
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Using isobutylene as an alkylation reagent requires a reaction under closed conditions, which can also be catalyzed by strong acids. In a mixed solvent of xylene and ketone, 85% phosphoric acid is used as a catalyst [8], and isobutylene is added to synthesize tert butylhydroquinone. The selectivity of the single tert butylation reaction can reach over 90%. Cationic resin [9] can also serve as a catalyst for this reaction, but the effect is not very ideal.
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Abstract: The Ministry of Health announced 4 national food safety standards in the Ministry of Health Announcement No. 12 in 2011, one of which is "GB 2760-2011 Food Safety National Standard Food Additives Use Standard", which was issued in June 2011 It will be officially implemented on the 20th. The preface of the standard clearly points out that some food classification systems of the 2007 edition of "GB 2760-2007 Hygienic Standards for the Use of Food Additives" have been adjusted.
DTBHQ and TBHQ are two food additives that are somewhat similar in function, but also differ in chemical structure and application areas. Let's take a look at the differences between these two food additives.First of all, there are differences in the chemical structures of DTBHQ and TBHQ, whose full name is Di-Tert-Butylhydroquinone, a di-tert-butylhydroquinone, and TBHQ, whose full name is Tert-Butylhydroquinone, also a hydroquinone, but it has only one tert-butyl group.
6. Safety EvaluationThe safety evaluation of TBHQ mainly includes toxicological evaluation and safety assessment. According to the results of many studies at home and abroad, the acute toxicity of TBHQ is low, and the oral LD50 of mice is 9.31g/kgbw, which belongs to the low toxicity category. In terms of safety assessment, the International Expert Committee on Food Additives (ECFA) considered TBHQ to be safe within the specified range of use.
Shandong Best Each shipment praised: quality products and excellent transportation build trust, TBHQ anti-fisheye agent shows its magic ability In the vast commercial ocean, Shandong Best Each has won the praise and trust of customers with its excellent product quality and outstanding transportation service.
Introduction and Applications of Terbutylhydroquinone (TBHQ)Introduction of TBHQ Terbutylhydroquinone (TBHQ) is a common food additive, which is widely used as antioxidant and preservative for edible oils, fats and oils, meat, fish, beverages and other foods. In this article, we will introduce the chemical properties, safety, uses and precautions for the use of TBHQ in detail. I.
Application cases of TBHQEdible oils and fats: Adding TBHQ to edible oils and fats can effectively slow down the rancidity process and prolong the shelf life of food. In practical application, TBHQ is usually added directly into oils and fats in the form of powder or liquid, and the usage amount is usually 0.01% to 0.02%.Meat products: Adding TBHQ to meat products can extend shelf life and prevent bacterial contamination and oxidative deterioration.
Precautions for use 1. The amount and proportion of terbutylhydroquinone used should be strictly controlled and should not exceed the maximum amount specified.2. Terbutylhydroquinone should be used in acidic medium, avoid mixing with alkaline substances.3. Terbutylhydroquinone should be stored in a cool and dry place, avoiding direct sunlight and high temperature environment.4. butylhydroquinone should be stored in stainless steel or glassware when in direct contact with food, avoid using plastic containers.5.
Antioxidant TBHQ: chemical structure, synthesis method, properties and uses, antioxidant mechanism, additive amount and use, safety evaluation, market demand and development trend, impact on the environment and treatment measures, evaluation of economic and social benefits, impact on human health and preventive measures1.Chemical structureThe chemical structure formula of TBHQ (tertiary butylhydroquinone) is C10H1402, which is a kind of effective antioxidant, widely used in food, cosmetics, medicine and other fields.2.Synthesis MethodsThe synthesis method of TBHQ mainly includes the following
Chinese nameHydroquinoneForeign nameHydroquinoneAliasHydroquinone, 1,4-benzenediolChemical formulaC6H6O2Molecular weight110.111CAS registration number123-31-9EINECS number204-617-8Melting point172 to 175 °CBoiling point286 °CDensity1.328 g/cm³AppearanceWhite crystalline powderFlash point141.6 ℃ApplicationBlack and white developer, anthraquinone dyes, azo dyes, rubber antioxidant, stabilizer and antioxidantSafety descriptionS26; S36/37/39; S61Hazard SymbolsXn; NHazard Descriptionr22; r40; r41; r43; r50; r68UN Dangerous Goods Number2662Soluble in alcohols and ethers, soluble in water, slightly s
Terbutylhydroquinone has good antioxidant effect. It has no bad taste and odor when added to any oil and oil-containing food. Good oil solubility, low toxicity, low dosage, it belongs to safe A(1) products, the antioxidant capacity is greater than propyl gallate (PG), 2,6-di-tert-butyl-p-cresol (BHT), tert-butyl-p-hydroxyanisole (BHA); added to food without bad odor.
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